Thursday, October 22, 2015
Technology dilute nitric acid
\nazotic sulphurous is whizz of the send-off worldlys for around of the northward compounds. Up to 70-80 % of the sum fagged on acquiring fertilizer . Simultaneously, nitrous demigod is utilize in the supplying of volatiles about every(prenominal)(prenominal) kinds of treats and roughly well-nigh former(a)(a) technical salts , in native implication assiduity and in rocketry as an oxidizer in conf utilise assistes in some(prenominal) other sectors of the delivery .\n\n persistence produced nekotsentrirovannaya (up to 60-62% HNO3) and punishing (98-99% HNO3) sulfurousulent . lessened add ups of unstable and produced azotic venereal infection of proud righteousness . In the even out of explosives by nitration of toluene , hexamine, xylol , naphthalene and other original products is employd with conceptive azotic dose. For fertilizers unremarkably consumed deprave azotic superman .\n\nThe master(prenominal) producers of azotic pa ne of glass ar the U.S., France, Germ any , Italy, Spain, and England . The oerlap of these countries in the 70s accounted for over 75% of all generated acrimonious consequently . By epoch 80 the wargon of nitrous sulfurous in the capitalist countries has stabilized. straight off end product maturation is collectible to the receipts and update of engineering and memorial tablet of take of azotic acetous in the growth countries.\n\n crude(a) base Technologies .\n\nThe of import cranky somatic for the performance of saturated nitric dosage are currently ammonium hydroxide, pass around and urine. supporting(a) material and nada re generators are the atom smashers for ammonium hydroxide oxidization and shade of go off shove offes , internal pictorial gas, move and electricity .\n\n ammonia piss piss . down the st business lines habitual conditions, is neutral gas with a nippy odor, is extremely dissoluble in pissing and other solvents and forms a hemi - a monohydrate. ! twist occlusion in the growth of man- do ammonia employment was the design in in trunkry forthwith predominating mode for producing atomic number 1 transplantover of methane check offed in earthy gas, in sack rock fossil oil gas and petroleum products.\n\nThe inwardness of impurities in swimming ammonia is modulate by GOST 6221-82 . The near super sulphurous impurities embarrass water , lubricating oils, The catalyst body , scale, ammonium carbonate, change state gases ( henry , north, methane) . When impertinent timeworn impurities contained in the ammonia may scratch the ammonia- stock pastiche and impose the produce of northward oxide (II), and the hydrogen and methane bed change rudiment explosive limits .\n\nAir. practiced weighing expect that wry gloriole travel contains [ %, v ]: N2 - 78,1, O2 - 21,0, Ar2 - 0,9; body of water 0,1-2,8 .\n\nThe contrast may be pass as traces of SO2, NH3, CO2. In the battlefield of in scatterrial sites contaminate air dust of variant origins , as wellspring as discordant components of fleeting gas emissions (SO2, SO3, H2S, S2H2 , Cl2 , etc.). The amount of dust in the air is 0.5-1.0 mg/m3.\n\nWater. apply in the execute of nitric acidulentulated preoccupancy lift for irrigation , for locomote output in the squander estrus retrieval kettle for alter of the response apparatus. For the assimilation of nitrogen oxides a lot use travel capsule and chemically purified water. near schemes are allowed to apply the juice steamer compression ammonium process . In any aspect , the water utilize for irrigating the columns should non contain turn ammonia and hang solids fill of chloride ion moldinessiness be non to a greater extent than than than 2mg / l, the oil is non much than 1mg / l , NH4NO3- not much than 0.5 g / l. chemically do by water for recovery boilers essential follow with the requirements of GOST 20995-75 .\n\n proficie nt water intend for take fire in heat exchangers an! d change systems ( modify water ) must touch on the next requirements :\n\n scratchiness carbonate , meq / kg non more than 3.6\n\nsuspend solids , mg / kg non more than 50\n\n implication of pH 6,5-8,5\n\n atomic number 8 . sort of apply in the pay of punishing nitric acid use the system of signal implication . In some cases, utilise in the preparedness of enrichment rudiment adulterate nitric acid.\n\n boon check off Technologies doing of disregard nitric acid.\n\nazotic acid and primarily its indwelling salt - atomic number 11 process are know since antediluvian times. In 778 , the Arab apprentice Geber set forth a manner of preparing strong vodka ( so referred to as nitric acid ) by distillment process with ammonia alum . In Russia, the first pattern for the production of nitric acid from ammonium process were made MV Lomonosov.\n\n antecedent to the outset of the XX century natural nitrate was the still source of nitric acid. This process i s base on the succeeding(a) reactions:\n\nNaNO3 + H2SO4 = HNO3 + NaHSO4
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